Project information
Crystal structures and bonding in non-metal compounds of the V., VI. , and VII. group of the periodic systém
- Project Identification
- GA203/98/0676
- Project Period
- 1/1998 - 1/2000
- Investor / Pogramme / Project type
-
Czech Science Foundation
- Standard Projects
- MU Faculty or unit
- Faculty of Science
The project deals with crystal structures and character of bonding in compounds cosntaining elements of the V., VI., and VII. group. The research will concentrate on the following classes of compounds: (a) structure of betaines of substituted (oligo) pho sphoric acids of the type B.P.X2Y, where B is a Lewis base, X=O,S, and Y=F,Cl, (b) structure of cyclodiphosphathianes and thiazadiphosphetidines, (c) structure of products of the reaction of amidophosphazenes with halogenides and oxohalogenides of sulfur and selenium, (d) structure od cyclic and linear P,N,S compounds, (e) structure of DA-complexes of selenium oxides, (f) structures solved in collaboration with other institutions. The metodics and experimental techniques developped during the previous p roject 203/95/1190, low temperature diffractometry and charge density calculations, will be used.
Publications
Total number of publications: 12
1998
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Halogenid-oxidy fosforečné a jejich donor-akceptorové komplexy.
2. seminář Pokroky v anorganické chemii. Sborník příspěvků., year: 1998
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The reaction of P3N3Cl5NH2 of with SOCl2: the crystal structures of P3N3Cl5NSO and Cl5N3P3OP3N3Cl5
Polyhedron, year: 1998, volume: 1998, edition: Vol.17